Gujarati
1.Solution and Colligative properties
medium

A non ideal solution was prepared by mixing $30\,ml$ chloroform and $50\,ml$ acetone. The volume of mixture will be

A

$> 80\,ml$

B

$< 80\,ml$

C

$= 80\,ml$

D

$> 80\,ml$

Solution

(b)Chloroform and acetone form a non-ideal solution, in which $A…..B$ type interaction are more than $A……A$ and $B……B$ type interaction due to $H$-bonding.

Hence, the solution shows, negative deviation from Raoult’s Law i.e.,

$\Delta {V_{mix}} = – ve$;       $\Delta {H_{mix}} = – \,ve$

$\therefore $ total volume of solution = less than $(30 + 50\,ml)$

or $ < \,80\,ml$

Standard 12
Chemistry

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