Gujarati
Hindi
General Principles and processes of Isolation of Elements
medium

Consider the following reactions at $1000\,^oC$

$(I)$ $Zn(s) + \frac{1}{2}{O_2}(g)\xrightarrow{\Delta }ZnO(g);{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} $      $\Delta {G^o} =  - 360{\mkern 1mu} \,kJ{\mkern 1mu} \,mo{l^{ - 1}}$

$(II)$ $C(s) + \frac{1}{2}{O_2}(g)\xrightarrow{\Delta }CO(g);{\mkern 1mu} {\mkern 1mu} $      $\Delta {G^o} =  - \,460{\mkern 1mu} \,kJ\,{\mkern 1mu} mo{l^{ - 1}}$

and choose the correct statement at  $1000\,^oC$

A

$ZnO$ is more stable than $CO$

 

B

$ZnO$ can be reduced to $Zn$ by $C$

 

C

$ZnO$ and $CO$ are formed at equal rate

D

$ZnO$ can not be reduced to $Zn$ by $C$

Solution

$\Delta {G^o}$ for overall reaction become $-ve.$

Standard 12
Chemistry

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