General Principles and processes of Isolation of Elements
hard

Consider two chemical reactions $(A)$ and $(B)$ that take place during metallurgical process:

$(A)$ $\mathrm{ZnCO}_{3(\mathrm{~s})} \longrightarrow \mathrm{A}{\longrightarrow} \mathrm{ZnO}_{(\mathrm{s})}+\mathrm{CO}_{2(\mathrm{~g})}$

$(B)$ $2 \mathrm{ZnS}_{(\mathrm{s})}+3 \mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{ZnO}_{(\mathrm{s})}+2 \mathrm{SO}_{2(\mathrm{~g})}$

The correct option of names given to them respectively is:

A

$(A)$ is calcination and $(B)$ is roasting

B

$(A)$ is roasting and $(B)$ is calcination

C

Both $(A)$ and $(B)$ are producing same product so both are calcination

D

Both $(A)$ and $(B)$ are producing same product so both are roasting

(JEE MAIN-2021)

Solution

$(A)$ $\mathrm{ZnCO}_{3}(\mathrm{~S}) \stackrel{\Delta}{\longrightarrow} \mathrm{ZnO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})$

Heating in absence of oxygen in calcination.

$(B)$ $2 \mathrm{ZNs}(\mathrm{s})+3 \mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{ZnO}(\mathrm{g})+2 \mathrm{SO}_{2}(\mathrm{~g})$

heating in presence of oxygen in roasting

Hence $(A)$ is calcination while $(B)$ in roasting

Standard 12
Chemistry

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