For a reaction $X + Y \to Z$, rate $ \propto \, [X]$. What is $(i)$ molecularity and $(ii)$ order of reaction ?
$(i)$ can't be defined, $(ii)\,\, 1$
$(i)\,\, 2, (ii)\,\, 2$
$(i)\,\, 1, (ii)\,\, 1$
$(i)\,\, 1, (ii)\,\, 2$
The rate of the reaction $CC{l_3}CHO + NO \to CHC{l_3} + NO + CO$ is given by Rate $ = K\,[CC{l_3}CHO]\,[NO]$. If concentration is expressed in moles/litre, the units of K are
Consider the kinetic data given in the following table for the reaction $A + B + C \rightarrow$ Product.
Experiment No. | $\begin{array}{c}{[ A ]} \\ \left( mol dm ^{-3}\right)\end{array}$ | $\begin{array}{c}{[ B ]} \\ \left( mol dm ^{-3}\right)\end{array}$ | $\begin{array}{c}{[ C]} \\ \left( mol dm ^{-3}\right)\end{array}$ | Rate of reaction $\left( mol dm ^{-3} s ^{-1}\right)$ |
$1$ | $0.2$ | $0.1$ | $0.1$ | $6.0 \times 10^{-5}$ |
$2$ | $0.2$ | $0.2$ | $0.1$ | $6.0 \times 10^{-5}$ |
$3$ | $0.2$ | $0.1$ | $0.2$ | $1.2 \times 10^{-4}$ |
$4$ | $0.3$ | $0.1$ | $0.1$ | $9.0 \times 10^{-5}$ |
The rate of the reaction for $[ A ]=0.15 mol dm ^{-3},[ B ]=0.25 mol dm ^{-3}$ and $[ C ]=0.15 mol dm ^{-3}$ is found to be $Y \times 10^{-5} mol dm d ^{-3} s ^{-1}$. The value of $Y$ i. . . . . . .
Why molecularity is applicable only for elementary reactions and order is applicable for elementary as well as complex reactions ?
Time required for completion of ionic reactions in comparison to molecular reactions is
The following results were obtained during kinetic studies of the reaction $2A+B$ $\to$ products
Experiment |
$[A]$ (in $mol\, L^{-1})$ |
$[B]$ (in $mol\, L^{-1})$ |
Initial rate of reaction (in $mol\, L^{-1}\,min^{-1})$ |
$I$ | $0.10$ | $0.20$ | $6.93 \times {10^{ - 3}}$ |
$II$ | $0.10$ | $0.25$ | $6.93 \times {10^{ - 3}}$ |
$III$ | $0.20$ | $0.30$ | $1.386 \times {10^{ - 2}}$ |
The time(in minutes) required to consume half of $A$ is