6-2.Equilibrium-II (Ionic Equilibrium)
medium

For a sparingly soluble salt $\mathrm{AB}_2$, the equilibrium concentrations of $\mathrm{A}^{2+}$ ions and $\mathrm{B}^{-}$ions are $1.2 \times 10^{-4} \mathrm{M}$ and $0.24 \times 10^{-3} \mathrm{M}$, respectively. The solubility product of $\mathrm{AB}_2$ is :

A

 $0.069 \times 10^{-12}$

B

 $6.91 \times 10^{-12}$

C

 $0.276 \times 10^{-12}$

D

 $27.65 \times 10^{-12}$

(JEE MAIN-2024)

Solution

$ \mathrm{AB}_{2(\mathrm{~s})} \rightleftharpoons \mathrm{A}_{(\mathrm{aq})}^{+2}+2 \mathrm{~B}_{(\mathrm{aq})}^{-} $

$ \mathrm{K}_{\mathrm{sp}}=\left[\mathrm{A}^{+2}\right]\left[\mathrm{B}^{-}\right]^2 $

$=1.2 \times 10^{-4} \times\left(2.4 \times 10^{-4}\right)^2 $

$=6.91 \times 10^{-12} \mathrm{M}^3$

Standard 11
Chemistry

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