For which type of reactions, order and molecularity have the same value ?

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For elementary reaction order and molecularity have the same value.

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The reaction $2{N_2}{O_5}$ $\rightleftharpoons$ $2N{O_2} + {O_2}$ follows first order kinetics. Hence, the molecularity of the reaction is

The concentration of $R$ in the reaction $R \rightarrow P$ was measured as a function of time and the following data is obtained:

$[R]$ (molar) $1.0$ $0.75$ $0.40$ $0.10$
$\mathrm{t}$ (min.) $0.0$ $0.05$ $0.12$ $0.18$

The order of the reaction is

  • [IIT 2010]

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The instantaneous rate of disappearance of $MnO_4^-$ ion in the following reaction is $4.56\times10^{-3}\,Ms^{-1}$,  $2MnO_4^-+ 10I^-+ 16 H^+ \to  2 Mn^{2+} + 5I_2 + 8H_2O$ The rate of appearance $I_2$ is