Gujarati
Hindi
General Principles and processes of Isolation of Elements
medium

Formation of $Ni(CO)_4$ and subsequent its decomposition into $Ni$ and $CO$ (recycled) makes basis of Mond's process

$Ni + 4CO \xrightarrow{{{T_1}}} Ni(CO)_4 \xrightarrow{{{T_2}}} Ni + 4CO$

$T_1$ and $T_2$ are :

A

$100\,^oC$,  $50\,^oC$

B

$50\,^oC$,  $100\,^oC$

C

$50\,^oC$,  $230\,^oC$

D

$230\,^oC$ ,  $50\,^oC$

Solution

Mond process is used for the refining of nickel.

Nickel is heated with CO to form highly volatile nickel tetracarbonyl.

it is then decomposed to pure nickel at high temperature.

$\mathrm{Ni}+4 \mathrm{CO} \stackrel{50^{\circ} \mathrm{C}}{\rightarrow} \mathrm{Ni}(\mathrm{CO})_{4} \stackrel{230^{\circ} \mathrm{C}}{\rightarrow} \mathrm{Ni}+4 \mathrm{CO}$

Thus $\mathrm{T}_{1}$ and $\mathrm{T}_{2}$ are $50^{\circ} \mathrm{C}$ and $230^{\circ} \mathrm{C}$ respectively.

Standard 12
Chemistry

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