Give important trends and anomalous properties of boron.
Certain important trends can be observed in the chemical behaviour of group-$13$ elements. The trichlorides, bromides and iodides of all these elements being covalent in nature are hydrolysed in water.
Species like tetrahedral $\left[\mathrm{M}(\mathrm{OH})_{4}\right]^{-}$and octahedral $\left[\mathrm{M}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}$, except in boron, exist in aqueous medium.
The monomeric trihalides, being electron deficient, are strong Lewis acids. Boron trifluoride easily reacts with Lewis bases such as $\mathrm{NH}_{3}$ to complete octet around boron.
It is due to the absence of $d$-orbitals that the maximum covalence of $B$ is $4$ . Since the $d$ orbitals are available with $\mathrm{Al}$ and other elements, the maximum covalence can be expected beyond $4$.
Most of the other metal halides (e.g., $\mathrm{AlCl}_{3}$ ) are dimerised through halogen bridging (e.g., $\mathrm{Al}_{2} \mathrm{Cl}_{6}$ ). The metal species completes its octet by accepting electrons from halogen in these halogen bridged molecules.
Which one is used as a bye-product in Serpeck's process
During metallurgy of aluminium bauxite is dissolved in cryolite because
For compound having the formula $GaAlCl _4$, the correct option from the following is
Anhydrous $AlCl_3$ is formed in
Which of the following cation can not give borax bead test ?