Gujarati
p-Block Elements - I
normal

The crystalline form of borax has

($A$) tetranuclear $\left[\mathrm{B}_4 \mathrm{O}_5(\mathrm{OH})_4\right]^{2-}$ unit

($B$) all boron atoms in the same plane

($C$) equal number of $s p^2$ and $s p^3$ hybridized boron atoms

($D$) one terminal hydroxide per boron atom

A

$C,D$

B

$A,C$

C

$A,C,B$

D

$A,C,D$

(IIT-2016)

Solution

The correct options are

$A$ Tetranuclear $\left[ B _4 O _5( OH )_4\right]^{2-}$ unit

$C$ Equal number of $sp ^2$ and $sp ^3$ hybridized boron atoms

$D$ One terminal hydroxide per boron atom

Correct formula of borax is $Na _2\left[B_4 O _5( OH )_4\right] \cdot 8 H _2 O$.

Borax has tetranuclear. $\left[ B _4 O _5( OH )_4\right]^{2-}$ unit.

Only two $B$ atom lies in the same plane.

Two Boron are $sp ^2 \&$ two are $sp ^3$ hybridised.

One terminal hydroxide is present per boron atom.

Hence, options $A, C$ and $D$ are correct.

Standard 11
Chemistry

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