The one which is unimolecular reaction is

  • A

    $2HI \to {H_2} + {I_2}$

  • B

    ${N_2}{O_5} \to {N_2}{O_4} + \frac{1}{2}{O_2}$

  • C

    ${H_2} + C{l_2} \to 2HCl$

  • D

    $PC{l_3} + C{l_2} \to PC{l_5}$

Similar Questions

For a reaction, $AB_5 \to AB + 4B$ The rate can be expressed in following ways

$\frac{{ - d[A{B_5}]}}{{dt}} = K[A{B_5}]$ ;    $\frac{{d[B]}}{{dt}} = {K_1}[A{B_5}]$

So the correct relation between $K$ and $K_1$ is

The results given in the below table were obtained during kinetic studies of the following reaction:

$2 A + B \longrightarrow C + D$

Experiment $[ A ] / molL ^{-1}$ $[ B ] / molL ^{-1}$ Initial $rate/molL$ $^{-1}$ $\min ^{-1}$
$I$ $0.1$ $0.1$ $6.00 \times 10^{-3}$
$II$ $0.1$ $0.2$ $2.40 \times 10^{-2}$
$III$ $0.2$ $0.1$ $1.20 \times 10^{-2}$
$IV$ $X$ $0.2$ $7.20 \times 10^{-2}$
$V$ $0.3$ $Y$ $2.88 \times 10^{-1}$

$X$ and $Y$ in the given table are respectively :

 

  • [JEE MAIN 2020]

For reaction a $A \to x\;P$, when $[A] = 2.2\,m\,M$, the rate was found to be $2.4\;m\,M\;{s^{ - 1}}$. On reducing concentration of $A$ to half, the rate changes to $0.6\;m\,M\;{s^{ - 1}}$. The order of reaction with respect to $A$ is

  • [AIIMS 2005]

In a reaction $2A + B \to {A_2}B$, the reactant $ A $ will disappear at

Rate constant for a reaction ${H_2} + {I_2} \to 2HI$ is $49$, then rate constant for reaction $2HI \to {H_2} + {I_2}$ is