p-Block Elements - I
medium

Which of the following is an electron deficient molecule?

A

$LiH$

B

$B_2H_6$

C

$LiBH_4$

D

$B_3N_3H_6$

Solution

$\mathrm{B}_{2} \mathrm{H}_{6}$ is electron deficient molecule because boron atom has three half-filled orbitals in an excited state.

The structure of $\mathrm{B}_{2} \mathrm{H}_{6}$ is represented as follows:

In it, two electrons of $\mathrm{B}$ -H bond are involved in the formation of three centre bond, these bonds are represented by a dotted line.

Hence, option A is correct.

Standard 11
Chemistry

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