6-2.Equilibrium-II (Ionic Equilibrium)
easy

$\mathrm{A}_{3} \mathrm{~B}_{2}$ is a sparingly soluble salt of molar mass $\mathrm{M}\left(\mathrm{g} \,\mathrm{mol}^{-1}\right)$ and solubility $\mathrm{x}\, \mathrm{g}\, \mathrm{L}^{-1}$. The solubility product satisfies $\mathrm{K}_{\mathrm{sp}}=a\left(\frac{\mathrm{x}}{\mathrm{M}}\right)^{5}$. The value of $a$ is ...... . (Integer answer)

A

$18$

B

$150$

C

$308$

D

$108$

(JEE MAIN-2021)

Solution

$\mathrm{A}_{3} \mathrm{~B}_{2}(\mathrm{~s}) \rightleftharpoons 3 \mathrm{~A}_{(\mathrm{xa})}^{+2}+2 \mathrm{~B}_{(4)}^{-3}$

$\quad\quad\quad\quad\quad\quad3 \mathrm{~s}\quad\quad \quad 2 \mathrm{~s}$

$\mathrm{~K}_{\mathrm{sp}}=(3 \mathrm{~s})^{3}(2 \mathrm{~s})^{2}$

$\mathrm{~K}_{\mathrm{SP}}=108 \mathrm{~S}^{5} \& \mathrm{~s}=(\mathrm{X} / \mathrm{M})$

$\mathrm{K}_{\mathrm{SP}}=108\left(\frac{\mathrm{x}}{\mathrm{m}}\right)^{5}$

$\text { given } \mathrm{K}_{\mathrm{SP}}=\mathrm{a}\left(\frac{\mathrm{x}}{\mathrm{m}}\right)^{5}$

comparing a $=108$

Standard 11
Chemistry

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