Gujarati
Hindi
General Principles and processes of Isolation of Elements
medium

$Ag_2S + NaCN + Zn \rightarrow Ag$

This method of extraction of $Ag$ by complex formation and then its displacement is called :

A

Parke's method

B

McArthur-Forest method

C

Serpeck method

D

Hall's method

Solution

Cyanide process is used for extraction of $Ag$ which is also called Mc-Arthur forest process.Reactions occurs in extraction of silver –

$Ag _2 S +4 NaCN \rightarrow 2 Na \left[ Ag ( CN )_2\right]+ Na _2 S$ (reversible reaction)

$4 Na _2 S +5 O _2+ H _2 O \rightarrow 2 Na _2 SO _4+4 NaOH +2 S$

and $2 Na \left[ Ag ( CN )_2\right]+ Zn \rightarrow Na _2\left[ Zn ( CN )_4\right]+2 Ag$

Standard 12
Chemistry

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