4.Chemical Bonding and Molecular Structure
medium

Assertion :Fluorine molecule has bond order one.
Reason : The number of electrons in the antibonding molecular orbitals is two less than that in bonding molecular orbitals.

A

If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.

B

If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.

C

If the Assertion is correct but Reason is incorrect.

D

If both the Assertion and Reason are incorrect.

(AIIMS-2008)

Solution

$MO$ electronic configuration of $F_2$ molecule. $\sigma 1{s^2},\,{\sigma ^*}1{s^2},\,\sigma 2{s^2},\,{\sigma ^*}2{s^2},\,\sigma 2p_x^2,\,\pi 2p_y^2 \approx \,\pi 2p_z^2,\,{\pi ^*}2p_y^2 \approx {\pi ^*}2p_z^2$ Thus there are $10$ electrons in bonding orbitals and $8$ electrons in antibonding orbitals. Thus, reason is true and it is also the correct explanation of assertion because Bond order $=$ $\frac{{{N_b} – {N_a}}}{2} = \frac{{10 – 8}}{2} = 1$

Standard 11
Chemistry

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