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12.Kinetic Theory of Gases
normal
At $0\,^oC$ , the value of the density of fixed mass of an ideal gas divided by its pressure is $x$ . At $100\,^oC$ , this value will be
A
$\frac {100}{273}\, x$
B
$\frac {273}{100}\, x$
C
$\frac {273}{373}\, x$
D
$x$
Solution
$\mathrm{PV}=\mathrm{nRT}$
$\mathrm{P} \times \frac{\mathrm{M}}{\rho}=\frac{\mathrm{M}}{\mathrm{M}_{\mathrm{W}}} \mathrm{RT}$
$\frac{\mathrm{P}}{\rho}=\frac{\mathrm{RT}}{\mathrm{M}_{\mathrm{w}}}=\frac{1}{\mathrm{x}}$ (given)
$\frac{\mathrm{R}(273)}{\mathrm{M}_{\mathrm{w}}}=\frac{1}{\mathrm{x}} \quad$ and $, \quad \frac{\mathrm{R}(373)}{\mathrm{M}_{\mathrm{W}}}=\frac{1}{\mathrm{x}_{2}}$
On dividing $\&$ solving
$\mathrm{x}_{2}=\frac{273}{373} \mathrm{x}$
Standard 11
Physics