General Principles and processes of Isolation of Elements
medium

In the electrolysis of alumina to obtain aluminium metal, cryolite is added mainly to

A

lower the melting point of alumina

B

dissolve alumina in molten cryolite

C

remove the impurities of alumina

D

increase the electrical conductivity

(AIEEE-2012)

Solution

Fused alumina $(Al_2O_3)$ is a bad conductor of electricity. Therefore, cryolite $(Na_3AlF_6)$ and fluorspar $(CaF_2)$ are added to purified alumina which not only make alumina a good conductor of electricity but also reduce the melting point of the mixture to around $1140\, K$.

Standard 12
Chemistry

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