4.Chemical Bonding and Molecular Structure
medium

Number of molecules having bond order $2$ from the following molecule is. . . . . . .  $\mathrm{C}_2, \mathrm{O}_2, \mathrm{Be}_2, \mathrm{Li}_2, \mathrm{Ne}_2, \mathrm{~N}_2, \mathrm{He}_2$

A

$1$

B

$2$

C

$5$

D

$8$

(JEE MAIN-2024)

Solution

$\left(12 \mathrm{e}^{-}\right): \sigma 1 \mathrm{~s}^2, \sigma^* 1 \mathrm{~s}^2, \sigma 2 \mathrm{~s}^2, \sigma^* 2 \mathrm{~s}^2\left[\pi 2 \mathrm{p}_{\mathrm{x}}^2=\pi 2 \mathrm{p}_{\mathrm{y}}^2\right]$

$\text { B.O. }=\frac{8-4}{2}=2$

$\mathrm{O}_2$

$\left(16 \mathrm{e}^{-}\right): \sigma 1 \mathrm{~s}^2, \sigma^* 1 \mathrm{~s}^2, \sigma 2 \mathrm{~s}^2, \sigma^* 2 \mathrm{~s}^2, \sigma 2 \mathrm{pz}^2$

${\left[\pi 2 \mathrm{p}_{\mathrm{x}}^2=\pi 2 \mathrm{p}_{\mathrm{y}}^2\right]\left[\pi^* 2 \mathrm{p}_{\mathrm{x}}^1=\pi^* 2 \mathrm{p}_{\mathrm{y}}^1\right]}$

$\text { B.O. }=\frac{10-6}{2}=2$

$\mathrm{Be}_2$

$\left(8 \mathrm{e}^{-}\right): \sigma 1 \mathrm{~s}^2, \sigma^* 1 \mathrm{~s}^2, \sigma 2 \mathrm{~s}^2, \sigma^* 2 \mathrm{~s}^2$

$\text { B.O. }=\frac{4-4}{2}=0$

$\text { Li }_2$

$\left(6 \mathrm{e}^{-}\right): \sigma 1 \mathrm{~s}^2, \sigma^* 1 \mathrm{~s}^2, \sigma 2 \mathrm{~s}^2$

Standard 11
Chemistry

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