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6-2.Equilibrium-II (Ionic Equilibrium)
medium
Solubility product of a salt $AB $ is $1 \times {10^{ - 8}}$ in a solution in which concentration of $A$ is ${10^{ - 3}}\,M$. The salt will precipitate when the concentration of $B$ becomes more than
A
${10^{ - 4}}\,M$
B
${10^{ - 7}}\,M$
C
${10^{ - 6}}\,M$
D
${10^{ - 5}}\,M$
Solution
(d) $[B] = \frac{{{K_{sp}}AB}}{{[A]}} = \frac{{1 \times {{10}^{ – 8}}}}{{{{10}^{ – 3}}}} = 1 \times {10^{ – 5}}\,M$
Where ionic product $>$ ${K_{sp}},\,ppt$ formed
$\therefore $ $B$ should be more then ${10^{ – 5}}\,M$.
Standard 11
Chemistry
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