Gujarati
6-2.Equilibrium-II (Ionic Equilibrium)
hard

Solubility product of a sulphide $MS$  is $3 \times {10^{ - 25}}$ and that of another sulphide $NS $ is $4 \times {10^{ - 40}}$. In ammoniacal solution

A

Only $NS$  gets precipitated

B

Only $MS $ gets precipitated

C

No sulphide precipitates

D

Both sulphides precipitate

Solution

(d)The concentration of ${S^{2 – }}$ions in group II is lowered by maintaining acidic medium in the presence of $N{H_4}Cl$. The ionization of ${H_2}S$ is supressed due to common ion effect. So the ionic product is less than solubility product.

Standard 11
Chemistry

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