p-Block Elements - I
medium

The function of fluorspar in the electrolytic reduction of alumina dissolved in fused cryolite $(N{a_3}Al{F_6})$ is

A

As a catalyst

B

To lower the temperature of the melt and to make the fused mixture very conducting

C

To decrease the rate of oxidation of carbon at the anode

D

None of the above

(IIT-1993)

Solution

Fluorspar $( CaF_2 )$ is added in small quantity in the electrolytic reduction of alumina dissolved in fused cryolite $( Na_3A l F_6)$. Addition of cryolite and fluorspar increases the electrical conductivity of alumina and lowers the fusion temperature to around $1140 \,K$.

Standard 11
Chemistry

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