The rate constant of esterification $(k) = k'\, [H_2O]$ rate constant of esterification $2.0\times 10^{-3}\,min^{-1}$ calculate $k'$.
The rate constant of esterification $(k) = k'\, [H_2O]$ rate constant of esterification $2.0\times 10^{-3}\,min^{-1}$ calculate $k'$.
$k=k^{\prime}\left[\mathrm{H}_{2} \mathrm{O}\right]$
$\begin{aligned} \therefore k^{\prime} =\frac{k}{\left[\mathrm{H}_{2} \mathrm{O}\right]}=\frac{2.0 \times 10^{-3} \mathrm{~min}^{-1}}{55.5 \mathrm{~mol} \mathrm{~L}^{-1}} \\ =0.036 \times 10^{-3} \mathrm{~mol}^{-1} \mathrm{~L} \mathrm{~min}^{-1} \\ =3.6 \times 10^{-5} \mathrm{~mol}^{-1} \mathrm{~L} \mathrm{~min}^{-1} \end{aligned}$
Similar Questions
During Kinetic study of reaction $2 A+B \rightarrow C+D$, the following results were obtained :
$A[M]$
$B[M]$
initial rate of
formation of $D$
$i$
$0.1$
$0.1$
$6.0 \times 10^{-3}$
$ii$
$0.3$
$0.2$
$7.2 \times 10^{-2}$
$ii$
$0.3$
$0.4$
$2.88 \times 10^{-1}$
$iv$
$0.4$
$0.1$
$2.40 \times 10^{-2}$
Based on above data, overall order of the reaction is $\qquad$
During Kinetic study of reaction $2 A+B \rightarrow C+D$, the following results were obtained :
| $A[M]$ | $B[M]$ |
initial rate of formation of $D$ |
|
| $i$ | $0.1$ | $0.1$ | $6.0 \times 10^{-3}$ |
| $ii$ | $0.3$ | $0.2$ | $7.2 \times 10^{-2}$ |
| $ii$ | $0.3$ | $0.4$ | $2.88 \times 10^{-1}$ |
| $iv$ | $0.4$ | $0.1$ | $2.40 \times 10^{-2}$ |
Based on above data, overall order of the reaction is $\qquad$
- [JEE MAIN 2024]
If the concentration of the reactants is increased, the rate of reaction
If the concentration of the reactants is increased, the rate of reaction
The concentration of $R$ in the reaction $R \rightarrow P$ was measured as a function of time and the following data is obtained:
$[R]$ (molar)
$1.0$
$0.75$
$0.40$
$0.10$
$\mathrm{t}$ (min.)
$0.0$
$0.05$
$0.12$
$0.18$
The order of the reaction is
The concentration of $R$ in the reaction $R \rightarrow P$ was measured as a function of time and the following data is obtained:
| $[R]$ (molar) | $1.0$ | $0.75$ | $0.40$ | $0.10$ |
| $\mathrm{t}$ (min.) | $0.0$ | $0.05$ | $0.12$ | $0.18$ |
The order of the reaction is
- [IIT 2010]
For reaction :
$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$
rate law is $R = K\, [NO_2]' [O_3]'$.
Which of these possible reaction mechanisms is consistent with the rate law?
Mechanism $I :$
$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)
Mechanism $II :$
$O_3(g) \rightleftharpoons O_2(g) + [O]$ (fast)
$NO_2(g) + [O] \to NO_3$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5$ (fast)
For reaction :
$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$
rate law is $R = K\, [NO_2]' [O_3]'$.
Which of these possible reaction mechanisms is consistent with the rate law?
Mechanism $I :$
$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)
Mechanism $II :$
$O_3(g) \rightleftharpoons O_2(g) + [O]$ (fast)
$NO_2(g) + [O] \to NO_3$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5$ (fast)
The reaction between $A$ and $B$ is first order with respect to $A$ and zero order with respect to $B$. Fill in the blanks in the following table:
Experiment
$[ A ] / mol\, ^{-1}$
$[ B ] / mol\, ^{-1}$
Initial rate $/$ $mol$ $L^{-1}$ $min$ $^{-1}$
$I$
$0.1$
$0.1$
$2.0 \times 10^{-2}$
$II$
-
$0.2$
$4.0 \times 10^{-2}$
$III$
$0.4$
$0.4$
-
$IV$
-
$0.2$
$2.0 \times 10^{-2}$
The reaction between $A$ and $B$ is first order with respect to $A$ and zero order with respect to $B$. Fill in the blanks in the following table:
| Experiment | $[ A ] / mol\, ^{-1}$ | $[ B ] / mol\, ^{-1}$ | Initial rate $/$ $mol$ $L^{-1}$ $min$ $^{-1}$ |
| $I$ | $0.1$ | $0.1$ | $2.0 \times 10^{-2}$ |
| $II$ | - | $0.2$ | $4.0 \times 10^{-2}$ |
| $III$ | $0.4$ | $0.4$ | - |
| $IV$ | - | $0.2$ | $2.0 \times 10^{-2}$ |