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General Principles and processes of Isolation of Elements
easy

These are following extraction process of silver but not :

A

as a side product in electrolytic refining of copper

B

Parke's process in which $Zn$ is used to extract silver by solvent extraction from molten lead

C

by reaction of silver sulphide with $KCN$ and then reaction of soluble complex with $Zn$

D

by heating $Na[Ag(CN)_2]$

Solution

The Parkes process is a process for removing silver from lead.

Electrolytic process gives the highest-purity metal product as well as the best recovery of valuable impurities. It is used for copper, nickel, lead, gold, and silver.

Reactions occurs in extraction of silver-

$Ag _2 S +4 NaCN \rightarrow 2 Na \left[ Ag ( CN )_2\right]+ Na _2 S$ (reversible reaction)

$2 Na \left[ Ag ( CN )_2\right]+ Zn \rightarrow Na _2\left[ Zn ( CN )_4\right]+2 Ag$

here we can also use $K$ instead of $Na$.

But by heating of $Na \left[ Ag ( CN )_2\right]$, $Ag$ is not produced as on and heating $Na \left[ Ag ( CN )_2\right]$ forms a complex product of $Ag$ and not simple $Ag$.

Standard 12
Chemistry

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