$K _{ a_1,}, K _{ a_2 }$ and $K _{ a_3}$ are the respective ionization constants for the following reactions $(a), (b),$ and $(c)$.

$(a)$ $H _{2} C _{2} O _{4} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{-}$

$(b)$ $HC _{2} O _{4}^{-} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{2-}$

$(c)$ $H _{2} C _{2} O _{4} \rightleftharpoons 2 H ^{+}+ C _{2} O _{4}^{2-}$

The relationship between $K_{a_{1}}, K_{ a _{2}}$ and $K_{ a _{3}}$ is given as

The first ionization constant of $H _{2} S$ is $9.1 \times 10^{-8}$. Calculate the concentration of $HS ^{-}$ ion in its $0.1 \,M$ solution. How will this concentration be affected if the solution is $0.1\, M$ in $HCl$ also? If the second dissociation constant of $H _{2} S$ is $1.2 \times 10^{-13}$, calculate the concentration of $S^{2-}$ under both conditions.

The $K_a$ of monobasic acid $A, B$ and $C$ are $10^{-6}, 10^{-8}$ and $10^{-10}$ respectively. The concentrations of $A, B$ and $C$ are respectively. $0.1\,M$, $0.01\, M$ and $0.001\, M$. Which of the following is correct for $pOH$ of $A, B$ and $C$ ?

The percentage of pyridine $(C_5H_5N)$ that forms pyridinium ion $(C_5H_5N^+H)$ in a $0.10\, M$ aqueous pyridine solution ($K_b$ for $C_5H_5N = 1.7 \times 10^{-9}$) is

Explain ionization and ionization constant in di and polyprotic acid.

Values of dissociation constant, $K_a$ are given as follows

Correct order of increasing base strength of the base $CN^-,F^-$ and $NO_2^-$ will be