A $0.1\, M$ solution of $HF$ is $1\%$ ionized. What is the $K_a$

  • A

    ${10^{ - 5}}$

  • B

    ${10^{ - 4}}$

  • C

    $3 \times {10^{ - 5}}$

  • D

    $3 \times {10^{ - 4}}$

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  • [AIIMS 2004]

$2\, gm$ acetic acid and $3\, gm$ sodium acetate are present in $100\, ml$. aqueous solution then what will be the $pH$ of solution if ionisation constant of acetic acid is $1.8 \times 10^{-5}$

${K_{C{H_3}COOH}} = 1.9 \times {10^{ - 5}}$. Calculate $pH$ at end point in titration of $0.1$ $M$ $C{H_3}COOH$ and $0.1$ $M$ $NaOH$.

What is the $pH$ of $0.001 \,M$ aniline solution? The ionization constant of aniline can be taken from Table . Calculate the degree of ionization of aniline in the solution. Also calculate the ionization constant of the conjugate acid of aniline.

Base $K _{ b }$
Dimethylamine, $\left( CH _{3}\right)_{2} NH$ $5.4 \times 10^{-4}$
Triethylamine, $\left( C _{2} H _{5}\right)_{3} N$ $6.45 \times 10^{-5}$
Ammonia, $NH _{3}$ or $NH _{4} OH$ $1.77 \times 10^{-5}$
Quinine, ( $A$ plant product) $1.10 \times 10^{-6}$
Pyridine, $C _{5} H _{5} N$ $1.77 \times 10^{-9}$
Aniline, $C _{6} H _{5} NH _{2}$ $4.27 \times 10^{-10}$
Urea, $CO \left( NH _{2}\right)_{2}$ $1.3 \times 10^{-14}$

Derive ${K_w} = {K_a} \times {K_b}$ and ${K_w} = p{K_a} \times p{K_b}$ for weak base $B$ and its conjugate acid ${B{H^ + }}$.