Boron fluoride exists as $BF_3$ but boron hydride doesn't exist as $BH_3$ . Give reason. In which form, does it exist ? Explain its structure.
In $\mathrm{BF}_{3}$, lone pair of fluorine gives back support of electrons to boron atom by $p \pi-p \pi$ back bonding. This delocalization of electrons reduces the deficiency of electrons and thus reduces Lewis acidic character and increases stability of $\mathrm{BF}_{3}$.
In $\mathrm{BH}_{3}$, there is no lone pair of electrons on $\mathrm{H}$ atom, therefore, $\mathrm{BH}_{3}$ dimerizes to give $\mathrm{B}_{2} \mathrm{H}_{6}$. $4$ terminal $\mathrm{H}$ atoms and$2$ boron atoms lie in one plane and above and below the plane. Sothere are two bridging $\mathrm{H}$-atoms.
Which of the following properties describes the diagooal relalionship between boron and silicon?
$Be$ and $Al$ exhibit many properties which are similar, but the two elements differ in :
Which elements of group $13$ possess both $+1$ and $+3$ oxidation state?
The correct order of atomic radii in group $13$ elements is
If $B-Cl$ bond has a dipole moment, explain why $BCl_3$ molecule has zero dipole moment.