General Principles and processes of Isolation of Elements
normal

Consider the following reactions at $1000\,^oC$

$(I)$  $Zn(s){\mkern 1mu}  + {\mkern 1mu} 1/2{\mkern 1mu} {O_2}(g){\mkern 1mu} \xrightarrow{\Delta }{\mkern 1mu} ZnO(g){\mkern 1mu} ;$      $\Delta {G^o}{\mkern 1mu}  = \,{\mkern 1mu}  - \,{\mkern 1mu} 360\,{\mkern 1mu} {\mkern 1mu} kJ{\mkern 1mu} \,{\mkern 1mu} mo{l^{ - 1}}$

$(II)$  $C(s){\mkern 1mu}  + {\mkern 1mu} 1/2{\mkern 1mu} {O_2}(g){\mkern 1mu} \xrightarrow{\Delta }{\mkern 1mu} CO(g){\mkern 1mu} ;$      $\Delta {G^o}{\mkern 1mu}  = {\mkern 1mu}  - \,{\mkern 1mu} 460{\mkern 1mu} {\mkern 1mu} \,kJ{\mkern 1mu} {\mkern 1mu} mo{l^{ - 1}}$

and choose the correct statement at $1000\,^oC$

A

$ZnO$ is more stable than $CO$

B

$ZnO$ can be reduced to $Zn$ by $C$

C

$ZnO$ and $CO$ are formed at equal rate

D

$ZnO$ can not be reduced to $Zn$ by $C$

Solution

From given reactions, Free energy of the reaction : 

$ZnO(g)\, + \,C(s)\,\,\xrightarrow[{1000\,{\,^o}C\,}]{\Delta }\,Zn(g)\, + \,CO\,(g),$ is negative

Standard 12
Chemistry

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