From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.

$(iii)$ $CH _{3} CHO ( g ) \rightarrow CH _{4}( g )+ CO ( g ) \quad$ Rate $=k\left[ CH _{3} CHO \right]^{3 / 2}$

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$(iii)$ Given rate $=k\left[ CH _{3} CHO \right]^{3 / 2}$

Therefore, order of $=\frac{3}{2}$

Dimension of $k=\frac{\text { Rate }}{\left[ CH _{3} CHO \right]^{\frac{3}{2}}}$

$=\frac{m o l\, L^{-1} \,s^{-1}}{\left(m o l \,L^{-1}\right)^{\frac{3}{2}}}$

$=\frac{m o l\, L^{-1} \,s^{-1}}{m o l^{\frac{3}{2}} \,L^{\frac{3}{2}}}$

$=L^{\frac{1}{2}} m o l^{\frac{1}{2}} s^{-1}$

Similar Questions

If a reaction has the experimental rate expression rate $= K [A]^2[B]$, if the concentration of $A$ is doubled and the concentration of $B$ is halved, the what happens to the reaction rate

The experimental data for the reaction $2A + {B_2} \to 2AB$ isThe rate equation for the above data is

Exp.

$[A]_0$

$[B]_0$

Rate (mole $s^{-1}$)

$(1)$

$0.50$

$0.50$

$1.6 \times {10^{ - 4}}$

$(2)$

$0.50$

$1.00$

$3.2 \times {10^{ - 4}}$

$(3)$

$1.00$

$1.00$

$3.2 \times {10^4}$

  • [AIPMT 1997]

The reaction $2{N_2}{O_5}$ $\rightleftharpoons$ $2{N_2}{O_4} + {O_2}$ is

Define following term / Give definition :

$(1)$ Elementary reaction

$(2)$ Complex reaction

For the reaction, $2A + B\,\to $ products , when the concentrations of $A$ and $B$ both were doubled, the rate of the reaction increased from $0.3\,mol\,L^{-1}\,s^{-1}$ to $2.4 \,mol\,L^{-1}\,s^{-1}.$ When the concentration of $A$ alone is doubled, the rate increased from $0.3\,mol\,L^{-1}\,s^{-1}$ to $0.6\,mol\,L^{-1}\,s^{-1}.$ Which one of the following statements is correct?

  • [JEE MAIN 2019]