Which of the following is an example of pseudo unimolecular reaction
$C{{H}_{3}}COOC{{H}_{3}}+{{H}_{2}}O\xrightarrow{{{H}^{+}}}C{{H}_{3}}COOH+C{{H}_{3}}OH$
$C{{H}_{3}}COOC{{H}_{3}}+{{H}_{2}}O\xrightarrow{O{{H}^{-}}}C{{H}_{3}}COOH+C{{H}_{3}}OH$
$2FeC{{l}_{3}}+SnC{{l}_{2}}\to SnC{{l}_{4}}+2FeC{{l}_{2}}$
$NaOH+HCl\to NaCl+{{H}_{2}}O$
For the decomposition of azoisopropane to hexane and nitrogen at $543$ $K ,$ the following data are obtained.
$t$ $(sec)$ | $P(m m \text { of } H g)$ |
$0$ | $35.0$ |
$360$ | $54.0$ |
$720$ | $63.0$ |
Calculate the rate constant.
The decomposition of $NH _{3}$ on $Pt$ surface is a zero order reaction. If the value of rate constant is $2 \times 10^{-4}\,mole $ $liter^{-1}\, sec ^{-1}$ The rate of appearance of $N _{2}$ and $H _{2}$ are respectively.
Which one of the following is wrongly matched
Order of radioactive disintegration reaction is
For the reaction : $2A + B \to A_2B$ ; the rate $= K[A]\, [B]^2$ with $K = 2.0\times10^{-6}\, lit^2\, mol^{-2}\, sec^{-1}$. Initial concentration of $A$ and $B$ are $0.2\, mol/lit$ and $0.4\, mol/lit$ respectively. Calculate the rate of reaction after $[A]$ is reduced to $0.12\, mol/litre$.