Which one of the following statements for the order of a reaction is incorrect?
Order can be determined only experimentally.
Order is not influenced by stoichiometric coefficient of the reactants.
Order of a reaction is sum of power to the concentration terms of reactants to express the rate of reaction.
Order of reaction is always whole number.
The reaction, $X + 2Y + Z \to N$ occurs by the following mechanism
$(i)$ $X + Y \rightleftharpoons M$ very rapid equilibrium
$(ii)$ $M + Z \to P$ slow
$(iii)$ $O + Y \to N$ very fast
What is the rate law for this reaction
The rate of the reaction :
$2N_2O_5 \rightarrow 4NO_2 + O_2$ can be written in three ways.
$\frac{-d[N_2O_5 ]}{dt} = k[N_2O_5]$
$\frac{d[NO_2 ]}{dt} = k'[N_2O_5]\,;$ $\frac{d[O_2 ]}{dt} = k"[N_2O_5]$
The relationship between $k$ and $k'$ and betweenk and $k''$ are
$2 NO +2 H _{2} \rightarrow N _{2}+2 H _{2} O$
The above reaction has been studied at $800^{\circ} C$. The related data are given in the table below.
Reaction serial number | Initial pressure of $H _{2}$ / $kPa$ | Initial Pressure of $NO /$ $kPa$ | Initial rate $\left(\frac{- dp }{ dt }\right) /( kPa / s )$ |
$1$ | $65.6$ | $40.0$ | $0.135$ |
$2$ | $65.6$ | $20.1$ | $0.033$ |
$3$ | $38.6$ | $65.6$ | $0.214$ |
$4$ | $19.2$ | $65.6$ | $0.106$ |
The order of the reaction with respect to $NO$ is $...........$
The rate law for reaction $A + 2B = C + 2D$ will be
The rate constant of the reaction $2H_2O_2(aq) \to 2H_2O(aq) + O_2(g)$ is $3\times10^{-3}\, min^{-1}$. At what concentration of $H_2O_2$, the rate of reaction will be $2\times10^{-4}\, M\, s^{-1}$ ? ............ $M$