From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.
$(iv)$ $C _{2} H _{5} Cl ( g ) \rightarrow C _{2} H _{4}( g )+ HCl ( g ) \quad$ Rate $=k\left[ C _{2} H _{5} Cl \right]$
From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.
$(iv)$ $C _{2} H _{5} Cl ( g ) \rightarrow C _{2} H _{4}( g )+ HCl ( g ) \quad$ Rate $=k\left[ C _{2} H _{5} Cl \right]$
$(iv)$ Given rate $=k\left[ C _{2} H _{5} Cl \right]$ Therefore, order of the reaction $=1$
Dimension of $k=\frac{\text { Rate }}{\left[ C _{2} H _{5} Cl \right]}$
$=\frac{\operatorname{mol}\, L ^{-1} \,s ^{-1}}{ mol \,L ^{-1}}$
$= s ^{-1}$
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A reaction involving two different reactants
A reaction involving two different reactants
- [AIEEE 2005]
The following results have been obtained during the kinetic studies of the reaction:
$2 A+B \rightarrow C+D$
Experiment
$[ A ] / mol L ^{-1}$
$[ B ] / mol L ^{-1}$
Initial rate of formation of $D / mol \,L ^{-1} \,min ^{-1}$
$I$
$0.1$
$0.1$
$6.0 \times 10^{-3}$
$II$
$0.3$
$0.2$
$7.2 \times 10^{-2}$
$III$
$0.3$
$0.4$
$2.88 \times 10^{-1}$
$IV$
$0.4$
$0.1$
$2.40 \times 10^{-2}$
Determine the rate law and the rate constant for the reaction.
The following results have been obtained during the kinetic studies of the reaction:
$2 A+B \rightarrow C+D$
| Experiment | $[ A ] / mol L ^{-1}$ | $[ B ] / mol L ^{-1}$ | Initial rate of formation of $D / mol \,L ^{-1} \,min ^{-1}$ |
| $I$ | $0.1$ | $0.1$ | $6.0 \times 10^{-3}$ |
| $II$ | $0.3$ | $0.2$ | $7.2 \times 10^{-2}$ |
| $III$ | $0.3$ | $0.4$ | $2.88 \times 10^{-1}$ |
| $IV$ | $0.4$ | $0.1$ | $2.40 \times 10^{-2}$ |
Determine the rate law and the rate constant for the reaction.
Which of the following is an example of pseudo unimolecular reaction
Which of the following is an example of pseudo unimolecular reaction