$0.2$  molar solution of formic acid is ionized $3.2\%$. Its ionization constant is

  • A

    $1 \times {10^{ - 12}}$

  • B

    $2.1 \times {10^{ - 4}}$

  • C

    $1.25 \times {10^{ - 6}}$

  • D

    $1 \times {10^{ - 14}}$

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$K _{ a_1,}, K _{ a_2 }$ and $K _{ a_3}$ are the respective ionization constants for the following reactions $(a), (b),$ and $(c)$.

$(a)$ $H _{2} C _{2} O _{4} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{-}$

$(b)$ $HC _{2} O _{4}^{-} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{2-}$

$(c)$ $H _{2} C _{2} O _{4} \rightleftharpoons 2 H ^{+}+ C _{2} O _{4}^{2-}$

The relationship between $K_{a_{1}}, K_{ a _{2}}$ and $K_{ a _{3}}$ is given as

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The dissociation constant of a substituted benzoic acid at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-4}$. The $\mathrm{pH}$ of a $0.01 \ \mathrm{M}$ solution of its sodium salt is

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