For reaction $2A + B \to $ products, the active mass of $ B $ is kept constant and that of $A$ is doubled. The rate of reaction will then

  • A

    Increase $  2$ times

  • B

    Increase $ 4$  times

  • C

    Decrease $ 2$  times

  • D

    Decrease $4$ times

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The elementary reaction $2SO_2(g) + O_2(g) \to 2SO_3(g)$ is carried out in $1\, dm^3$ vessel and $2\,dm^3$ vessel separately. The ratio of the reaction velocities will be

For which type of reactions, order and molecularity have the same value ?

Consider the reaction :

$Cl_2(aq) + H_2S(aq) \to  S(s) + 2H^+(aq) + 2Cl^-(aq)$

The rate equation for this reaction is rate $= k[Cl_2][H_2S]$ Which of these mechanisms is/are consistent with this rate equation ?

$A.\,C{l_2} + {H_2}S \to {H^ + } + C{l^ - } + C{l^ + } + H{S^- }$  (slow)

$C{l^ + } + H{S^ - } \to {H^ + } + C{l^ - } + {S}$   (fast)

$B.\, H_2S  \Leftrightarrow  H^+ + HS^-$   (fast equilibrium)

$Cl_2 + HS^-\to  2Cl^-+ H^+ + S$ (slow)

For the following parallel chain reaction. What will be that value of overall half-life of $A$ in minutes ?

Given that  $\left[ {\frac{{{{\left[ B \right]}_t}}}{{{{[C]}_t}}} = \frac{{16}}{9}} \right]$

$A\,\xrightarrow{{{K_1}\, = \,2\, \times \,{{10}^{^{ - 3}\,}}{S^{ - 1}}}}4B$

$A\to C$

In a reaction between $A$ and $B$, the initial rate of reaction $\left(r_{0}\right)$ was measured for different initial concentrations of $A$ and $B$ as given below:

$A/mol\,\,{L^{ - 1}}$ $0.20$ $0.20$ $0.40$
$B/mol\,\,{L^{ - 1}}$ $0.30$ $0.10$ $0.05$
${r_0}/mol\,\,{L^{ - 1}}\,\,{s^{ - 1}}$ $5.07 \times 10^{-5}$ $5.07 \times 10^{-5}$ $1.43 \times 10^{-4}$

What is the order of the reaction with respect to $A$ and $B$?