If $pK_a =\, -\,log K_a=4$ for a weak acid $HX$ and $K_a= C\alpha ^2$ then Van't Haff factor when $C = 0.01\,M$ is
$1.01$
$1.02$
$1.10$
$0.20$
$K _{ a_1,}, K _{ a_2 }$ and $K _{ a_3}$ are the respective ionization constants for the following reactions $(a), (b),$ and $(c)$.
$(a)$ $H _{2} C _{2} O _{4} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{-}$
$(b)$ $HC _{2} O _{4}^{-} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{2-}$
$(c)$ $H _{2} C _{2} O _{4} \rightleftharpoons 2 H ^{+}+ C _{2} O _{4}^{2-}$
The relationship between $K_{a_{1}}, K_{ a _{2}}$ and $K_{ a _{3}}$ is given as
The ionisation constant of acetic acid is $1.8 \times 10^{-5}$. The concentration at which it will be dissociated to $2\%$, is
Dissociation constat of weak acid $HA$ is $1.8 \times {10^{ - 4}}$ calculate Dissociation constant of its conjugate base ${A^ - }$
What is the $pH$ of $0.001 \,M$ aniline solution? The ionization constant of aniline can be taken from Table . Calculate the degree of ionization of aniline in the solution. Also calculate the ionization constant of the conjugate acid of aniline.
Base | $K _{ b }$ |
Dimethylamine, $\left( CH _{3}\right)_{2} NH$ | $5.4 \times 10^{-4}$ |
Triethylamine, $\left( C _{2} H _{5}\right)_{3} N$ | $6.45 \times 10^{-5}$ |
Ammonia, $NH _{3}$ or $NH _{4} OH$ | $1.77 \times 10^{-5}$ |
Quinine, ( $A$ plant product) | $1.10 \times 10^{-6}$ |
Pyridine, $C _{5} H _{5} N$ | $1.77 \times 10^{-9}$ |
Aniline, $C _{6} H _{5} NH _{2}$ | $4.27 \times 10^{-10}$ |
Urea, $CO \left( NH _{2}\right)_{2}$ | $1.3 \times 10^{-14}$ |
Accumulation of lactic acid $(HC_3H_5O_3),$ a monobasic acid in tissues leads to pain and a feeling of fatigue. In a $0.10\, M$ aqueous solution, lactic acid is $3.7\%$ dissociates. The value of dissociation constant, $K_a,$ for this acid will be