The solubility of a salt of weak acid $( A B )$ at $pH 3$ is $Y \times 10^{-3} mol L ^{-1}$. The value of $Y$ is

. . . . . (Given that the value of solubility product of $A B \left( K _{ sp }\right)=2 \times 10^{-10}$ and the value of ionization constant of $H B \left( K _{ a }\right)=1 \times 10^{-8}$ )

When $100 \ mL$ of $1.0 \ M \ HCl$ was mixed with $100 \ mL$ of $1.0 \ M \ NaOH$ in an insulated beaker at constant pressure, a temperature increase of $5.7^{\circ} C$ was measured for the beaker and its contents (Expt. $1$). Because the enthalpy of neutralization of a strong acid with a strong base is a constant $\left(-57.0 \ kJ \ mol ^{-1}\right)$, this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. $2$), $100 \ mL$ of $2.0 \ M$ acetic acid $\left(K_a=2.0 \times 10^{-5}\right)$ was mixed with $100 \ mL$ of $1.0 M \ NaOH$ (under identical conditions to Expt. $1$) where a temperature rise of $5.6^{\circ} C$ was measured.

(Consider heat capacity of all solutions as $4.2 J g ^{-1} K ^{-1}$ and density of all solutions as $1.0 \ g mL ^{-1}$ )

$1.$ Enthalpy of dissociation (in $kJ mol ^{-1}$ ) of acetic acid obtained from the Expt. $2$ is

$(A)$ $1.0$ $(B)$ $10.0$ $(C)$ $24.5$ $(D)$ $51.4$

$2.$ The $pH$ of the solution after Expt. $2$ is

$(A)$ $2.8$ $(B)$ $4.7$ $(C)$ $5.0$ $(D)$ $7.0$

Give the answer question $1$ and $2.$

What is the $pH$ of the resulting solution when equal volumes of $0.1\, M\, NaOH$ and $0.01\, M\, HCl$ are mixed?

Calculate $pH$ of $0.02$ $mL$ $ClC{H_2}COOH$. Its ${K_a} = 1.36 \times {10^{ - 3}}$ calculate its $pK_{b}$,

A monoprotic acid in a $0.1\,\,M$ solution ionizes to $0.001\%$. Its ionisation constant is

The dissociation constant of a substituted benzoic acid at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-4}$. The $\mathrm{pH}$ of a $0.01 \ \mathrm{M}$ solution of its sodium salt is