Let observations are denoted by $x _{i}$ for $1 \leq i< 2 n$

$\bar{x}=\frac{\sum x_{i}}{2 n}=\frac{(a+a+\ldots+a)-(a+a+\ldots+a)}{2 n}$

$\Rightarrow \overline{ x }=0$

and $\sigma_{ x }^{2}=\frac{\sum x _{i}^{2}}{2 n }-(\overline{ x })^{2}=\frac{ a ^{2}+ a ^{2}+\ldots+ a ^{2}}{2 n }-0= a ^{2}$

$\Rightarrow \sigma_{x}=a$

Now, adding a constant $b$ then $\overline{ y }=\overline{ x }+ b =5$

$\Rightarrow b =5$

and $\sigma_{y}=\sigma_{x}$ (No change in S.D.) $\Rightarrow a=20$

$\Rightarrow a^{2}+b^{2}=425$